6.0 Conclusions.
The original intent of this series of papers was to resurrect the old
quantum theory of Niels Bohr and Arnold Sommerfeld and, together with some
input from modern quantum mechanics show that a theory of atomic structure
could, for single electron atoms and ions, be developed in which the
electron was interpreted as a real physical particle. With the incorporation
of magnetic dipole coupling, it is proposed that this objective has been
largely accomplished. This is considered to be a reasonable claim at this
stage because the resurrected theory can now predict all that the modern
quantum mechanics theory of atomic structure can predict. Further refinement
in the latter theory, i.e. the Lamb Shift, has had to make recourse to
additional techniques within quantum electrodynamics. Because of the
philosophical intent of the resurrected Bohr/Sommerfeld theory, it will need
to introduce this variation without recourse to quantum electrodynamics or
similar disciplines. This will be the subject of the next paper.
Albeit the above statement on the maturity of the resurrected theory is
considered justifiable at this stage, it must still be viewed as somewhat
embryonic. This is because essentially, only the hydrogen atom has been
considered in detail, and only to the point of fine structure splitting. To
provide further substance to the theory, not only will it be necessary to
incorporate an explanation for the Lamb Shift, but also a sound mathematical
model for the hyperfine structure will need to be added. Both of these
additions will require a physical interpretation in keeping with the
original objective. Furthermore, it would also be very desirable to extend
the theory to cover at the very least simple multi-electron atoms. However,
this would be, as is well known, severely restricted by the difficulties
inherent in solving three body, (and more), dynamic problems. Despite the
fact that in the modern quantum mechanics theory of atomic structure, the
electron is viewed as a probabilistic wavefunction, it is, strangely,
subject to the same difficulties.
The comparison of the two theories, as so far developed, in Section 5.0, is
from the mathematical point of view, favourable, minor differences aside.
However, when the comparison is extended to include physical attributes,
some anomalies result. Extending the comparison is justified despite the
fact that the electron is viewed so differently in the quantum mechanics
theory because that theory still makes extensive reference to such physical
parameters as spin, angular momentum, magnetic moment and relativistic mass
increase when discussing the electron. The extended comparison centres
exclusively around the quantum numbers used to characterise the electron
orbital energy levels. The main consequence of this comparison is that in
the quantum mechanics theory, the lack of s orbital angular momentum,
results in the necessity for two separate equations to describe the orbital
energy for all orbitals. One equation is required for s orbitals, in which
the Darwin term is included but spin-orbit coupling excluded, and a second
equation for all other orbitals with the Darwin term excluded and spin-orbit
coupling included. The only terms common are those for the gross energy
levels resulting from the basic central coulomb force and the "relativistic
mass increase" of the electron.
In the resurrected Bohr/Sommerfeld theory only one equation is necessary
incorporating the appropriate terms for the gross energy levels, the
relativistic electron mass increase and all magnetic dipole coupling
effects. All of these terms appearing in all orbitals. This is considered a
superior aspect of the Bohr/Sommerfeld theory over the quantum mechanics.
Within the Bohr/Sommerfeld theory it has been possible to ascribe real
physical meanings to all of the parameters involved and which appears free
of apparent anomalies. Possible mechanisms have been identified for electron
spin and photon emission, from which it has been possible to derive all
except one of the so called Selection Rules. The one exception is for
transitions in which Dnj = ± 2. These have been excluded in
the resurrected theory for orbit transition path geometrical reasons. In the
quantum mechanics theory, exclusion is for the inner quantum number change
only. However, in this regard, it is noted that the orbital angular momentum
Selection Rule governing transitions, is, even with spin-orbit coupling
incorporated, still nf *, (or l), because only that quantum number
is subject to a direct change when a photon emission occurs.
To complete the current phase of development, in addition to the
incorporation of the Lamb Shift and the hyperfine structure, it will be
useful to demonstrate the physical characteristics of all orbitals, the
electron transition paths between them, and the strengths of the emitted
spectra. These will be the subject of future papers.
Finally, as in previous papers in this series, the emission spectra as
predicted by this theory are shown in Appendix C. If the Lamb Shift effect
is removed from [6], the spectra of Appendix C are seen to compare very
favourably provided allowance is made for the small differences in the
values of the constants used.
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P.G.Bass, April 2008
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