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6 Conclusions.The results achieved in this series of papers to resurrect the Bohr/Sommerfeld old quantum theory of atomic structure have been fully discussed and summarised in Section 5 above. These final comments will therefore be restricted to the veracity of the overall development, and its one possibly perceived point of contention, the manner of determination of the electron spin matter wave radius.
This theory is truly not just a resurrection of the old quantum theory of
atomic structure, because it recognises and uses throughout the development,
the duality of the existence of matter. That combined with the old quantum
theory enabled this entire development to be derived from just two basic
postulates, those of Planck's quantum energy and de Broglie's matter wave
quantum momentum. From the inception of these in [6] through to this paper,
the mathematical development, with the exception of the subject discussed
below, has been rigorous, with no unsound assumptions, and in which the only
approximations taken have been to discard third and higher relativistic
terms, that have a negligible impact on the results to the accuracy and
precision targeted.
The one exception to the above statement is the manner in which the spin
matter wave radius has been determined. In a theory of atomic structure in
which the electron is treated as a real physical particle, albeit with a
dual corpuscular/wave function existence, and spin is a real parameter, it
is necessary to know with great precision all of the contributing attributes
of that particle. One of the critical requirements in this, and in fact also
in the quantum mechanics version, is that the electron conform to the spin
angular momentum quantum criteria, howsoever the concept of electron spin is
defined. To do that with the electron as treated here, it is first necessary
to know accurately and precisely the value of electron spin angular rate.
Secondly, bearing in mind the manner in which electron transitions have been
defined, the only manner in which the above criteria can be met is, in
conjunction with its spin rate, for the electron spin matter wave radius to
be a variable. Consequently, it is further necessary to know accurately and
with adequate precision the value of this parameter. With the electron as an
integral part of an atom, there is no known method with which either of
these two parameters can be measured experimentally. Similarly, there is no
known way in which they can be determined to the accuracy and precision
required purely theoretically, even given the manner of spin inducement
proposed in this series of papers. Accordingly, it is therefore necessary to
resort to the semi-empirical method of determination adopted here. In doing
so it is therefore not unreasonable to tailor the determination process to
provide results that match experimentally derived data. This of course is
only acceptable, provided that the determination process follows a logical
procedure, that integrates smoothly with the rest of the development. It is
proposed that this is indeed the case here, as exemplified with particularly
the discussion of the initiation of the transition process in Section 5.4
above.
That point accepted, the results obtained here are in excellent agreement
with those in the literature. A detailed examination of them, and their
numerical calculations, may be obtained from the spreadsheets in which they
are computed. See Appendix A.
Finally, any theory of atomic structure does not end with the development to the fine structure level and, in future papers, this theory will be further developed to the level of the hyperfine structure, and to cover the concepts of transition probabilities and spectral intensities, as well as investigation of the potential additions highlighted in the previous Section.
P5 Version 1.1.1
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P.G.Bass, April 2008
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